Nazarov Cyclization
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YouTubeOrganic Chemistry with Lluís Llorens Palomo
Nazarov Cyclization
The Nazarov Cyclization is the acid catalyzed ring-closure of divinyl ketones for the synthesis of cyclopentenones. Reaction mechanism: 1. Coordination of the Lewis acid to the carbonyl group and formation of a pentadienyl cation. 2. Conrotatory ring closure delivers a cyclic carbocation. 3. Elimination of the β-hydrogen. 4. Tautomerization of ...
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